If you remember one number from CPA1, make it the CO/CO₂ ratio. It's how the trade decides, in a single figure, whether an appliance is burning safely. This guide explains why it's a ratio, how it's calculated, and the limits that trigger action. It's study material; only a Gas Safe registered engineer may carry out the work.
Why a ratio, not just CO?
You might expect to judge combustion on the raw CO figure alone. The problem is dilution: if a little extra air leaks into the sample, or there's excess air in the products, it waters down CO and CO₂ by the same proportion. Raw CO would drop and flatter a poor appliance. But because both gases dilute together, the ratio between them stays almost unchanged — so it reflects the quality of combustion itself, not how much air happened to mix in. That's why it's the reliable indicator.
How it's calculated
The ratio is simply CO divided by CO₂, with both as the same kind of figure. Since CO is read in ppm and CO₂ as a percentage, you convert first. The key conversion:
1% = 10,000 ppm
Put CO into % : 200 ÷ 10,000 = 0.02%.
Ratio = 0.02 ÷ 9 = 0.0022 — comfortably below the action level. Modern boilers often achieve 0.001–0.002. (Your analyser does this automatically, but understanding it is what's tested.)
The action level: 0.0040
Where the manufacturer gives no specific figure, the agreed action level — specified by BS 7967 and Gas Safe guidance — is a CO/CO₂ ratio of 0.0040, alongside a CO figure of 350 ppm in the products. At or below 0.0040 is generally acceptable; above it, combustion is unsatisfactory and must be investigated before the appliance is left in service. In practice many treat 0.004 as a "soft" target and 0.008 as a "hard" limit, investigating anything in between.
Reading O₂ alongside
The oxygen reading helps explain a ratio. Lots of excess air (high O₂) with low CO is inefficient but not dangerous; too little air (low O₂) pushes the mixture rich and the CO — and the ratio — climbs. The ratio tells you whether there's a problem; O₂ and the other readings help you understand why.
- Ratio over raw CO: dilution lowers CO and CO₂ together, so the ratio stays reliable.
- Calculation: CO ÷ CO₂, same units. 1% = 10,000 ppm.
- Action level: 0.0040 ratio (and 350 ppm CO) where no manufacturer figure applies.
- ≤ 0.0040 generally acceptable; above = investigate before leaving in service.
- Soft/hard: 0.004 soft target, 0.008 hard limit in common practice.
- Manufacturer limits take precedence over the generic figures.
- O₂ explains the ratio (excess air vs rich mixture).
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Dilution lowers CO and CO₂ together, so their ratio stays steady — a reliable measure of how cleanly the appliance burns.
1% = 10,000 ppm, so a CO reading in ppm is divided by 10,000 to put it into percent.
0.0040, specified by BS 7967 and Gas Safe guidance, alongside a 350 ppm CO figure.
200 ppm = 0.02%; 0.02 ÷ 9 = 0.0022 — below the 0.0040 action level.
At or below 0.0040 is generally acceptable; above it needs investigation before leaving the appliance in service.
The agreed key action levels are CO ≤ 350 ppm and ratio ≤ 0.0040 where the manufacturer is silent.
0.004 is often the soft target and 0.008 the hard limit, with investigation of anything in between.
0.0040 is the fallback; a stated manufacturer limit takes precedence.
Too little air pushes the mixture rich, CO climbs and the ratio rises.
A high ratio means too much CO relative to CO₂ — incomplete combustion that must be investigated.
0.0040, 350 ppm, 1% = 10,000 ppm. Burn them into memory.
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